JAMB Chemistry 2024 past questions and answers

20 questions. Try each one, then open the answer to check yourself and read the explanation.

Question 1

Energy Changes

A chemical reaction involving the absorption of heat is said to be

  1. A.isothermic
  2. B.endothermic
  3. C.exothermic
  4. D.thermostatic
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Answer: B (endothermic)

Explanation

A reaction that takes in heat from the surroundings is endothermic (ΔH positive).

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Question 2

Metals and their Compounds

What element is common in the two alloys: brass and bronze?

  1. A.Zinc
  2. B.Tin
  3. C.Lead
  4. D.Copper
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Answer: D (Copper)

Explanation

Brass is copper and zinc; bronze is copper and tin. Copper is in both.

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Question 4

Carbon and its Compounds

Bubbling of CO2 into Ca(OH)2(aq) a white precipitate is formed. In the presence of carbon dioxide (in excess) the white precipitate disappears. The reason for this is

  1. A.calcium hydrogen carbonate is precipitated and then dissolve
  2. B.calcium carbonate is formed which on reaction dissolves
  3. C.concentration of the solution has occurred with the deposition of calcium hydroxide
  4. D.calcium carbonate is formed which on reaction with further carbondioxide forms soluble calcium hydrogen carbonate
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Answer: D (calcium carbonate is formed which on reaction with further carbondioxide forms soluble calcium hydrogen carbonate)

Explanation

CO2 first gives insoluble CaCO3 (milky); excess CO2 and water turn it into soluble Ca(HCO3)2, so the precipitate clears.

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Question 6

Introduction to Organic Chemistry

The organic compound above is

Diagram for this question
  1. A.2, 3-dimethylpent-2-ene
  2. B.2,3-dimethylpent-2,3-ene
  3. C.3,4-dimethyl
  4. D.3,4-dimethylpentene
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Answer: A (2, 3-dimethylpent-2-ene)

Explanation

The longest chain has 5 carbons. Numbering from the end nearer the double bond puts the C=C at carbon 2 and the methyl groups on carbons 2 and 3: 2,3-dimethylpent-2-ene.

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Question 10

Solubility and Solutions

The solubility graph of a solid Y (molecular mass=160) as shown below. 1000cm3 of a saturated solution of Y at 80°C is cooled to 40°C. The weight of Y crystalized out would be

Diagram for this question
  1. A.12g
  2. B.16g
  3. C.18g
  4. D.14g
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Answer: B (16g)

Explanation

From the graph, solubility is 0.4 mol/dm3 at 80 °C and 0.3 mol/dm3 at 40 °C. 0.1 mol crystallises: 0.1 × 160 = 16 g.

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Question 14

Hydrogen, Oxygen and Oxides

Which of the following is a neutral oxide

  1. A.NO2
  2. B.Al2O3
  3. C.CO
  4. D.CO2
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Answer: C (CO)

Explanation

CO reacts with neither acids nor alkalis, so it is neutral; NO2 and CO2 are acidic and Al2O3 is amphoteric.

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Question 15

Electrolysis

CuSO4(aq) is electrolyzed using platinum electrodes with a current of 0.193 amperes for 2 hours. How many grams of copper are deposited at the cathode? [Cu= 63.5 F=96500 coulombs]

  1. A.0.500g
  2. B.0.457g
  3. C.0.914g
  4. D.1.000g
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Answer: B (0.457g)

Explanation

Q = It = 0.193 × 7200 = 1389.6 C. Cu2+ needs 2 × 96500 C per mole, so mass = 1389.6/193000 × 63.5 ≈ 0.457 g.

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Question 17

Redox Reactions

Write out the values of a, b and c respectively in the equation. aCu + bHNO3 → aCu(NO3)2 + 4H2O + cNO

  1. A.3:8:2
  2. B.4:1:2
  3. C.8:3:2
  4. D.2:8:3
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Answer: A (3:8:2)

Explanation

The balanced equation is 3Cu + 8HNO3 → 3Cu(NO3)2 + 4H2O + 2NO, so a = 3, b = 8, c = 2.

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Question 18

Petroleum and Coal

A compound used as an 'anti-knock' in automobile engines is

  1. A.Glycerol
  2. B.n-heptane
  3. C.lead tetra-ethyl
  4. D.Tetramethylsilane
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Answer: C (lead tetra-ethyl)

Explanation

Tetraethyl lead was added to petrol to stop knocking (n-heptane actually causes knocking).

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Question 19

Gas Laws

Which of the compounds has the lowest vapour density? [O= 16, Cl= 35.5, H= 1, C= 12]

  1. A.Propanol
  2. B.Ethanoic acid
  3. C.Ethanal
  4. D.Dichloromethane
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Answer: C (Ethanal)

Explanation

Vapour density = Mr/2. Propanol 60, ethanoic acid 60, ethanal 44, dichloromethane 85; ethanal gives the lowest (22).

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Question 21

Volumetric Analysis

Calculate the volume of 0.1mH2SO4 that will be required to neutralize 45.0cm3 of a 0.2 MNaOH?

  1. A.20.0cm3
  2. B.10.0cm3
  3. C.45.0cm3
  4. D.30.0cm3
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Answer: C (45.0cm3)

Explanation

H2SO4 + 2NaOH → Na2SO4 + 2H2O. Moles NaOH = 0.2 × 0.045 = 0.009, so acid = 0.0045 mol; volume = 0.0045/0.1 = 0.045 dm3 = 45.0 cm3.

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Question 25

Mole Concept and Stoichiometry

The Avogadro number of 23g of sodium is the same as that of

  1. A.16g of oxygen molecules
  2. B.1g of hydrogen molecules
  3. C.35.5g of chlorine molecules
  4. D.32g of oxygen molecules.
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Answer: D (32g of oxygen molecules.)

Explanation

23 g of sodium is 1 mole of atoms. 32 g of O2 is also 1 mole of molecules; the others are half a mole.

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Question 27

Metals and their Compounds

One of the uses of copper (II) tetraoxosulphate (VI) is

  1. A.fungicide
  2. B.fertilizer
  3. C.purifier
  4. D.disinfectant
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Answer: A (fungicide)

Explanation

Copper(II) sulphate mixed with lime makes Bordeaux mixture, sprayed on crops to kill fungi.

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Question 28

Nitrogen and its Compounds

In the above diagram X can be

Diagram for this question
  1. A.a solution of lead trioxonitrate(V)
  2. B.a solution of sodium dioxonitrate (III) and ammonium chloride
  3. C.concentrated tetraoxosulphate (VI) acid and sodium trioxonitrate (IV)
  4. D.a solution of sodium trioxonitrate(V) and ammonium chloride
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Answer: B (a solution of sodium dioxonitrate (III) and ammonium chloride)

Explanation

Nitrogen is made in the laboratory by warming sodium dinitrate(III) (NaNO2) with ammonium chloride; the gas is collected over water.

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Question 29

Carbohydrates, Proteins and Amines

Which of the following is a polysaccharide

  1. A.mannose
  2. B.dextrose
  3. C.starch
  4. D.glucose
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Answer: C (starch)

Explanation

Starch is a long chain of glucose units; the others are single sugars (monosaccharides).

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Question 30

Gas Laws

The total pressure of mixture of 80.0g of oxygen gas and 56.0g of nitrogen gas is 1.8 atm. Calculate the partial pressure of oxygen gas in the mixture [O=16, N=14]

  1. A.1.0 atm
  2. B.0.8 atm
  3. C.1.4 atm
  4. D.1.2 atm
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Answer: A (1.0 atm)

Explanation

O2: 80/32 = 2.5 mol; N2: 56/28 = 2 mol. Mole fraction of O2 = 2.5/4.5, so p = 2.5/4.5 × 1.8 = 1.0 atm.

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Question 35

Volumetric Analysis

The graph below illustrates the pH changes for the titration of a

Diagram for this question
  1. A.weak acid versus strong base
  2. B.strong acid versus strong base
  3. C.weak acid versus weak base
  4. D.strong acid versus weak base
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Answer: B (strong acid versus strong base)

Explanation

The pH starts low (about 2), ends high (about 12) and jumps steeply around 7 at the end point, which is typical of a strong acid against a strong base.

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Question 36

Petroleum and Coal

Coal gas consists of carbon(II)oxide, hydrogen and

  1. A.air
  2. B.nitrogen
  3. C.methane
  4. D.argon
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Answer: C (methane)

Explanation

Coal gas from heating coal is mainly hydrogen, methane and carbon(II) oxide.

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Question 39

Metals and their Compounds

Which of the following oxide will remain unchanged when heated in hydrogen gas?

  1. A.Fe2O3
  2. B.CuO
  3. C.ZnO
  4. D.PbO2
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Answer: C (ZnO)

Explanation

Hydrogen reduces oxides of less reactive metals such as iron, copper and lead, but zinc is too reactive, so ZnO is left unchanged.

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Question 40

Chemical Bonding

The bonding that does not involve the formation of a new substance is

  1. A.covalent
  2. B.metallic
  3. C.electrovalent
  4. D.co-ordinate
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Answer: B (metallic)

Explanation

Metallic bonding holds atoms of the same metal together in a sea of electrons; it does not combine different elements into a compound.

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