JAMB Chemistry 1999 Question 20

Question 20

Redox Reactions

What is observed when aqueous solutions of each of tetraoxosulphate (VI) acid, potassium trioxoiodate (V) and potassium iodide are mixed together?

  1. A.A white precipitate is formed
  2. B.A green precipitate is formed
  3. C.The mixture remains colourless
  4. D.The mixture turns reddish brown.
Show the answer and explanation

Answer: D (The mixture turns reddish brown.)

Explanation

In acid, iodate(V) oxidizes iodide to iodine: IO3− + 5I− + 6H+ → 3I2 + 3H2O. The iodine colours the solution reddish brown.