JAMB Chemistry 1994 Question 23

Question 23

Electrolysis

What volume of oxygen measured at s.t.p would be liberated on electrolysis by 9650 coulombs of electricity? [Molar volume of gas = 22.4 dm3, F = 96,500 C mol-1]

  1. A.22.4 dm3
  2. B.11.2 dm3
  3. C.1.12 dm3
  4. D.0.560 dm3
Show the answer and explanation

Answer: D (0.560 dm3)

Explanation

9650 C is 0.1 F. Making one mole of O2 needs 4 F (4OH− → O2 + 2H2O + 4e−), so 0.1 F gives 0.025 mol = 0.025 × 22.4 = 0.560 dm3.