JAMB Chemistry 1987 Question 41

Question 41

Hydrocarbons

Which of the following compounds will give a precipitate with an aqueous ammoniacal solution of copper (I) chloride?

  1. A.CH3CH = CHCH3
  2. B.CH3C ≡ CCH3
  3. C.HC ≡ C–CH2CH3
  4. D.CH2 = CH–CH = CH2
Show the answer and explanation

Answer: C (HC ≡ C–CH2CH3)

Explanation

Only alkynes with a terminal ≡C–H (an acidic hydrogen) form a red precipitate of copper(I) acetylide. But-1-yne has one; but-2-yne and the alkenes do not.