JAMB Chemistry 1986 Question 3

Question 3

Gas Laws

10 cm3 of hydrogen fluoride gas reacts with 5 cm3 of dinitrogen difluoride gas (N2F2) to form 10 cm3 of a single gas. Which of the following is the most likely equation of the reaction?

  1. A.HF + N2F2 → N2HF3
  2. B.2HF + N2F2 → 2NHF2
  3. C.2HF + N2F2 → N2H2F4
  4. D.HF + 2N2F2 → N4HF5.
Show the answer and explanation

Answer: B (2HF + N2F2 → 2NHF2)

Explanation

By Gay-Lussac's law the volumes 10 : 5 : 10 give the mole ratio 2 : 1 : 2. Only 2HF + N2F2 → 2NHF2 has this ratio and is balanced.