Unilorin Post-UTME Chemistry 2023 (Model questions) past questions and answers

10 questions. Try each one, then open the answer to check yourself and read the explanation.

Question 1

Periodic Table

Which of the following elements has the highest electronegativity?

  1. A.sodium
  2. B.chlorine
  3. C.fluorine
  4. D.oxygen
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Answer: C (fluorine)

Explanation

Fluorine is the most electronegative element (3.98 on the Pauling scale), higher than oxygen (3.44) and chlorine (3.16).

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Question 2

Chemical Bonding

What is the shape of methane molecule?

  1. A.linear
  2. B.tetrahedral
  3. C.trigonal planar
  4. D.bent
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Answer: B (tetrahedral)

Explanation

Carbon in CH4 has four bonding pairs, which spread out as far as possible into a tetrahedral shape (bond angle 109.5°).

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Question 3

Rates of Reaction

The rate of a chemical reaction can be increased by

  1. A.increasing the temperature
  2. B.decreasing the concentration of reactants
  3. C.adding a catalyst
  4. D.two of the above
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Answer: D (two of the above)

Explanation

Both raising the temperature and adding a catalyst speed up a reaction; lowering the concentration slows it. So 'two of the above' is right.

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Question 4

Chemical Formulae and Equations

What is the molecular formula of a compound that contains 40% carbon, 6.7% hydrogen and 53.3% oxygen by mass? Take the relative molecular mass of the compound as 180 (C = 12, H = 1, O = 16)

  1. A.CH2O
  2. B.C4H8O4
  3. C.C6H12O6
  4. D.C5H8O7
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Answer: C (C6H12O6)

Explanation

Mole ratio C : H : O = 40/12 : 6.7/1 : 53.3/16 = 3.33 : 6.7 : 3.33 = 1 : 2 : 1, so the empirical formula is CH2O (mass 30). 180 ÷ 30 = 6, giving C6H12O6.

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Question 5

Kinetic Theory and States of Matter

The process by which a gas changes directly to a solid is called

  1. A.melting
  2. B.sublimation
  3. C.deposition
  4. D.condensation
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Answer: C (deposition)

Explanation

Gas turning straight into solid is deposition. Sublimation is the reverse (solid straight to gas) and condensation is gas to liquid.

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Question 6

Hydrocarbons

What is the main component of natural gas?

  1. A.ethane
  2. B.butane
  3. C.propane
  4. D.methane
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Answer: D (methane)

Explanation

Natural gas is mostly methane (about 70-90%), with smaller amounts of ethane, propane and butane.

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Question 7

Atomic Structure

The principle that states that no two electrons in an atom can have the same set of four quantum numbers is

  1. A.Pauli Exclusion principle
  2. B.Hund's rule
  3. C.Aufbau principle
  4. D.Heisenberg Principle
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Answer: A (Pauli Exclusion principle)

Explanation

The Pauli exclusion principle says no two electrons in an atom share all four quantum numbers, so an orbital holds at most two electrons of opposite spin.

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Question 8

Carbon and its Compounds

Which of the following is the best conductor of electricity?

  1. A.diamond
  2. B.graphite
  3. C.silicon
  4. D.sulphur
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Answer: B (graphite)

Explanation

In graphite each carbon uses only three electrons for bonding; the fourth is delocalised and free to carry current. Diamond and sulphur are insulators and silicon is only a semiconductor.

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Question 9

Mole Concept and Stoichiometry

How many molecules are there in 11.2dm3 of ammonia at s.t.p? (G.M.V = 22.4dm3 at stp, NA = 6.02 × 1023mol−1)

  1. A.3 × 1020
  2. B.3 × 1021
  3. C.3 × 1022
  4. D.3 × 1023
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Answer: D (3 × 1023)

Explanation

Moles = 11.2 ÷ 22.4 = 0.5 mol. Molecules = 0.5 × 6.02 × 1023 ≈ 3 × 1023.

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Question 10

Atomic Structure

What is the electronic configuration of chloride ion (Cl−)?

  1. A.1s22s22p63s23p5
  2. B.1s22s22p63s23p6
  3. C.1s22s22p63s23p4
  4. D.1s22s22p63s23d103p6
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Answer: B (1s22s22p63s23p6)

Explanation

Chlorine (17 electrons) ends in 3p5; the chloride ion gains one electron, giving 18 electrons ending in 3p6.

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