JAMB Chemistry 1979 Question 48

Question 48

Qualitative Analysis

A piece of metal (M) is dissolved in nitric acid and the resulting solution is treated with a small quantity of sodium hydroxide to produce a white precipitate (B) which redissolves on the addition of excess alkali. The precipitate (B) when ignited in a crucible produces the oxide of the metal (M). The metal M is

  1. A.Zn
  2. B.Cu
  3. C.Al
  4. D.Au
  5. E.Ca
Show the answer and explanation

Answer: A (Zn)

Explanation

Zinc dissolves in nitric acid, and its white hydroxide dissolves in excess NaOH (it is amphoteric). Copper gives a blue precipitate and calcium's does not redissolve; aluminium is made passive by nitric acid.